Center for Research in Biological Chemistry and Molecular Materials (CIQUS)
Department of Physical Chemistry and Department of Organic Chemistry
University of Santiago de Compostela, Spain
Functional Materials and Nanotechnology Group
Adsorbent Materials (project PID2021-122923NB-I00)
Within the large variety of materials and components included in electrical and electronic equipment (EEE), in this project (Recovery of scarce and valuable Metals from e-Waste by means of tailor-made adsorbent materials), we specially focus on a specific fraction, the so-called printed circuit boards (PCB). They account for an estimated 3-5 wt.% of e-waste, and are made up of more than 30% by weight of different metal elements, distributed in form of metal layers, joining materials, complex mixtures of metals and multielement alloys.
More specifically, the main proposal of this research is the efficient copper, precious metals (gold, silver, platinum, and palladium, selected for their high value), and critical metals (antimony, considered as a feasibility model of recovery of elements other than noble and transition metals) uptake from the PCB lixiviates produced using novel adsorbents designed for this task, and the following recovery of metals adsorbed, evaluating their re-usability, applying adsorption-desorption cycles.
The two proposed tailor-made classes of materials are hierarchically porous multifunctional activated carbons obtained by using polyacrylonitrile (PAN)-based block copolymers (BCs) as precursors, and functional porous organic polymers (POPs).
The work packages of the project are detailed in the Scheme.
Project outputs
V Rahimi, A Ferreiro-Salgado, D Gómez-Díaz, MS Freire, J González-Álvarez
Separation and Purification Technology 2024, 344, 127110
Adsorption of anionic wood dyes on KOH-activated carbons from Pinus radiata sawdust
CH Pimentel, R Castro-Agra, MS Freire, D Gómez-Díaz, J González-Álvarez
Biomass Conversion and Biorefinery 2024, 1-20
S/N/O-Enriched Carbons from Polyacrylonitrile-Based Block Copolymers for Selective Separation of Gas Streams
D Gómez-Díaz, L Domínguez-Ramos, G Malucelli, MS Freire, J González-Álvarez, M Lazzari
Polymers 2024, 16 (2), 269 [open access]
V Rahimi, EA Inzulza-Moraga, D Gómez-Díaz, MS Freire, J González-Álvarez
Environmental Science and Pollution Research 2024, 1-16
Continuous Adsorption of Acid Wood Dyes onto an Activated Carbon Prepared from Pine Sawdust
CH Pimentel, MS Freire, D Gómez-Díaz, J González-Álvarez
Applied Sciences 2024, 14 (2), 841
Congress contributions
6th International Conference on Green Chemistry and Sustainable Engineering (GreenCHEM-24), Lisboa, Portugal, July 24-26:
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V. Rahimi, D. Gómez-Díaz, M.S. Freire, M. Lazzari, J. González-Álvarez "KOH-activated carbons prepared from biomoss precursors for copper recovery from waste printed circuit boards"
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C.H. Pimentel, A. Rial-Pomares, V. Rahimi, M.S. Freire, D. Gómez-Díaz, M. Lazzari, J. González-Álvarez "Removal of methylene blue and malochife green from aqueous solutions by adsorpfion onto KOH aclivated carbon from almond shells"
to be completed ...